Experimental analysis of the thermal behavior of a GM cryocooler based on linear system theory

Closed cycle refrigerators for cryogenic temperatures (cryocoolers) provide a convenient solution in a wide range of applications, from low temperature physics to cryopumping, superconducting magnets or low noise infrared sensing. Understanding in detail the physical mechanisms underlying cryocooler operation is then of practical and fundamental interest. This paper deals with the analysis as a linear dynamical system of a GM cryocooler operation, considered over a limited range of temperature around a setpoint. The method is interesting as a way to model the thermal behavior of the refrigerator that can be effective in systematic analysis of cryocoolers thermal behaviour and design of temperature controllers

Experimental analysis of the thermal behavior of a GM cryocooler based on linear system theory

Closed cycle refrigerators for cryogenic temperatures (cryocoolers) provide a convenient solution in a wide range of applications, from low temperature physics to cryopumping, superconducting magnets or low noise infrared sensing. Understanding in detail the physical mechanisms underlying cryocooler operation is then of practical and fundamental interest. This paper deals with the analysis as a linear dynamical system of a GM cryocooler operation, considered over a limited range of temperature around a setpoint. The method is interesting as a way to model the thermal behavior of the refrigerator that can be effective in systematic analysis of cryocoolers thermal behaviour and design of temperature controllers

Microscopic Mechanism and Kinetics of Ice Formation at Complex Interfaces: Zooming in on Kaolinite

Most ice in nature forms thanks to impurities which boost the exceedingly low nucleation rate of pure supercooled water. However, the microscopic details of ice nucleation on these substances remain largely unknown. Here, we have unraveled the molecular mechanism and the kinetics of ice formation on kaolinite, a clay mineral playing a key role in climate science. We find that the formation of ice at strong supercooling in the presence of this clay is twenty orders of magnitude faster than homogeneous freezing. The critical nucleus is substantially smaller than that found for homogeneous nucleation and, in contrast to the predictions of classical nucleation theory (CNT), it has a strong 2D character. Nonetheless, we show that CNT describes correctly the formation of ice at this complex interface. Kaolinite also promotes the exclusive nucleation of hexagonal ice, as opposed to homogeneous freezing where a mixture of cubic and hexagonal polytypes is observed

Quantum coherent transport in a three-arm beam splitter and a Braess paradox

The Braess paradox encountered in classical networks is a counterintuitive phenomenon when the flow in a road network can be impeded by adding a new road or, more generally, the overall net performance can degrade after addition of an extra available choice. In this work, we discuss the possibility of a similar effect in a phase-coherent quantum transport and demonstrate it by example of a simple Y-shaped metallic fork. To reveal the Braess-like partial suppression of the charge flow in such device, it is proposed to transfer two outgoing arms into a superconducting state. We show that the differential conductance-vs-voltage spectrum of the hybrid fork structure varies considerably when the extra link between the two superconducting leads is added and it can serve as an indicator of quantum correlations which manifest themselves in the quantum Braess paradox.Comment: 9 pages, 3 figures, the author version presented at the Quantum 2017 Workshop (Torino, Italy, 7-13 May 2017) and submitted to the International Journal of Quantum Information; v2: reference 9 added and the introduction extende

Ice formation on kaolinite: Insights from molecular dynamics simulations

The formation of ice affects many aspects of our everyday life as well as important technologies such as cryotherapy and cryopreservation. Foreign substances almost always aid water freezing through heterogeneous ice nucleation, but the molecular details of this process remain largely unknown. In fact, insight into the microscopic mechanism of ice formation on different substrates is difficult to obtain even if state-of-the-art experimental techniques are used. At the same time, atomistic simulations of heterogeneous ice nucleation frequently face extraordinary challenges due to the complexity of the water-substrate interaction and the long time scales that characterize nucleation events. Here, we have investigated several aspects of molecular dynamics simulations of heterogeneous ice nucleation considering as a prototypical ice nucleating material the clay mineral kaolinite, which is of relevance in atmospheric science. We show via seeded molecular dynamics simulations that ice nucleation on the hydroxylated (001) face of kaolinite proceeds exclusively via the formation of the hexagonal ice polytype. The critical nucleus size is two times smaller than that obtained for homogeneous nucleation at the same supercooling. Previous findings suggested that the flexibility of the kaolinite surface can alter the time scale for ice nucleation within molecular dynamics simulations. However, we here demonstrate that equally flexible (or non flexible) kaolinite surfaces can lead to very different outcomes in terms of ice formation, according to whether or not the surface relaxation of the clay is taken into account. We show that very small structural changes upon relaxation dramatically alter the ability of kaolinite to provide a template for the formation of a hexagonal overlayer of water molecules at the water-kaolinite interface, and that this relaxation therefore determines the nucleation ability of this mineral

Ice Formation on Kaolinite: Insights from Molecular Dynamics Simulations

The formation of ice affects many aspects of our everyday life as well as technologies such as cryotherapy and cryopreservation. Foreign substances almost always aid water freezing through heterogeneous ice nucleation, but the molecular details of this process remain largely unknown. In fact, insight into the microscopic mechanism of ice formation on different substrates is difficult to obtain even via state-of-the-art experimental techniques. At the same time, atomistic simulations of heterogeneous ice nucleation frequently face extraordinary challenges due to the complexity of the water-substrate interaction and the long timescales that characterize nucleation events. Here, we have investigated several aspects of molecular dynamics simulations of heterogeneous ice nucleation considering as a prototypical ice nucleating material the clay mineral kaolinite, which is of relevance in atmospheric science. We show via seeded molecular dynamics simulations that ice nucleation on the hydroxylated (001) face of kaolinite proceeds exclusively via the formation of the hexagonal ice polytype. The critical nucleus size is two times smaller than that obtained for homogeneous nucleation at the same supercooling. Previous findings suggested that the flexibility of the kaolinite surface can alter the time scale for ice nucleation within molecular dynamics simulations. However, we here demonstrate that equally flexible (or non flexible) kaolinite surfaces can lead to very different outcomes in terms of ice formation, according to whether or not the surface relaxation of the clay is taken into account. We show that very small structural changes upon relaxation dramatically alter the ability of kaolinite to provide a template for the formation of a hexagonal overlayer of water molecules at the water-kaolinite interface, and that this relaxation therefore determines the nucleation ability of this mineral

Universality of transport properties of ultra-thin oxide films

We report low-temperature measurements of current-voltage characteristics for highly conductive Nb/Al-AlOx-Nb junctions with thicknesses of the Al interlayer ranging from 40 to 150 nm and ultra-thin barriers formed by diffusive oxidation of the Al surface. In the superconducting state these devices have revealed a strong subgap current leakage. Analyzing Cooper-pair and quasiparticle currents across the devices, we conclude that the strong suppression of the subgap resistance comparing with conventional tunnel junctions originates from a universal bimodal distribution of transparencies across the Al-oxide barrier proposed earlier by Schep and Bauer. We suggest a simple physical explanation of its source in the nanometer-thick oxide films relating it to strong local barrier-height fluctuations which are generated by oxygen vacancies in thin aluminum oxide tunnel barriers formed by thermal oxidation.Comment: revised text and a new figur